A research team from the Department of Electrical and Electronic Information Engineering at Toyohashi University of Technology developed a chlorine (Cl) substituted Na3SbS4 solid electrolyte for use in all-solid-state sodium (Na) ion batteries. Compared to the sample without a Cl substitution, the ionic conductivity of the Na3SbS4 solid electrolyte where sulfur (S) was partially substituted with Cl improved by up to three times. The team also demonstrated that the Cl-substituted Na3SbS4 has a crystal structure framework that allows Na ions to move easier in three dimensions, and they discovered that the Cl substitution showed superior stability with Na metal anodes.
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Sodium solid electrolyte combining high conductivity with electrochemical stability
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